Determination of Nickel Chloride concentration in Nickel plating baths

Nickel chloride plays a key role in nickel plating baths, a galvanic process used to coat various materials, including iron, copper, brass, steel and zamak, for both decorative and technical-functional purposes. The composition of the nickel plating bath can be modulated by varying the concentration of components and operating conditions, allowing specific coating characteristics to be obtained according to application requirements. Nickel chloride, in particular, is essential to ensure proper anodic dissolution and improve the conductivity of the bath. Monitoring and analysis of its concentration is critical to ensure uniform nickel deposition and avoid defects in the coating, such as burning or nodularity.

Method

Test type: End Point.

Time testing: 4 minutes
Analysis sessions with multiple samples are possible up to a maximum of 16 tests for CDR GalvanLab®.

Sample Treatment

The analysis is carried out on the nickel bath. Dilute the sample before the use.

Test Principle

Nickel Chloride content is determined, after dilution, by reaction with a chromogen. The test has a total duration of 4 minutes at the end of which a spectrophotometric reading is taken: the signal detected is directly correlated with the concentration of Nickel Chloride.

Calibration curve

Calibration curve was obtained by correlating the CDR method with the reference method.

Calibration curve Nickel Chloride in Nickel bath

Measuring range

AnalysesMeasuring rangeResolutionRepeatability
Nickel chloride nickel bath25 - 90 g/L0.100 g/L0.6 g/L

Reagent test Kits

Code *400170: 100 test
Code *400175: 10 test
The reagents have a shelf-life of 12 months

The chemical analysis instrument for electroplating baths

CDR GalvanLab®

  • Complete analysis panel, supplied already configured
  • Up to 16 determinations simultaneously
  • Possibility of carrying out analyses of the same sample
  • Integrated printer
  • Full connections (LAN - USB - Bluetooth barcode/QR code reader)